Where do I get POT file?
You have to create it using a tool like Poedit.
Where do I place the file?
That's entirely up to you. commonly it's in a sub-folder called languages
. Then you need to reference it within your theme's functions.php file using something like:
load_theme_textdomain( 'my_theme_textdomain', get_template_directory() . '/languages' );